To explore these challenges and their environmental impact, this study proposes a hybrid sustainable infrastructure that integrates photovoltaic solar energy for the production and storage of green hydrogen, with PEMFC fuel cells and a hybrid Power-to-Electricity (PtE) and. To explore these challenges and their environmental impact, this study proposes a hybrid sustainable infrastructure that integrates photovoltaic solar energy for the production and storage of green hydrogen, with PEMFC fuel cells and a hybrid Power-to-Electricity (PtE) and. This review explores the advancements in solar technologies, encompassing production methods, storage systems, and their integration with renewable energy solutions. It examines the primary hydrogen production approaches, including thermochemical, photochemical, and biological methods. Green hydrogen is increasingly recognized as a sustainable energy vector, offering significant potential for the industrial sector, buildings, and sustainable transport. As countries work to establish infrastructure for hydrogen production, transport, and energy storage, they face several. This study assesses the feasibility of integrating hydro and solar power with a Hydrogen-based Electrical Energy Storage System (H2EESS) at the Serra da Mesa hy-droelectric Brazilian power plant.